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Iron Man Mark 7: Hero's Edition of Avengers of the Marvel Cinematic Universe
This Iron Man Head can be unmasked, but the face within isn't designed to easily come out for separate use, basically you can take the front off to unmask him, but you can't take his face and use it on any other Nendoroid.
https://www.goodsmile.info/en/product/3711/Nendoroid+Iron+Man+Mark+7+Hero+s+Edition.html